About Deca-BDE

Decabromodiphenyl Ether (Deca-BDE) is a highly effective brominated flame retardant which is used to prevent fires in plastics for electrical and electronic equipment as well as in textiles.

Deca BDE compound chart

Deca-BDE is used in plastics for electrical and electronic equipment (housings of computers, TV set, etc), in the transportation sector (i.e. automotive industry) and in construction and building (i.e. wires and cables, pipes, etc). It is also used as a flame retardant in textile back coating in furniture to comply with fire safety standards in public places and buildings and to comply with more stringent fire safety requirements for the home in countries such as Ireland, the United Kingdom and the United Sates.

Other relevant documents
Deca-BDE factsheet
Deca-BDE applications factsheet
Deca-BDE use in the automotive sector

Consumer protection

It is recognized that flame retardants play a critical role in making homes, hospitals, offices, cars and public transportation safer from the life-threatening consequences of fire.

Flame retardants allow longer escape times for those in the presence of a fire, as well as longer response times and less advanced fires for firefighters. It is estimated escape times can be up to 15 times longer when flame retardants are present, providing increased survival chances for those in close proximity.

A recent study by the University of Surrey (click here) estimates that flame retardants have been responsible for a 20 percent reduction in fire deaths in the United Kingdom in recent years. Statistics for the UK alone estimate that over 3.000 lives have been saved since 1988 as a result of the legislation mandating that upholstered furniture be made with a high level of fire resistance [DTI document]

Deca-BDE is believed to be the most effective flame retardant available in a wide range of different applications. In that sense, the role it plays on fire safety is unquestionable. A recent cost-benefit study developed by the Swedish National Testing and Research Institute (SP) in cooperation with the Risk Assessment Institute at Utrecht University, with the aim to quantifying the gains from using flame retardants in TVs, has demonstrated that Deca-BDE used in televisions avoids 11 full house fires per million TV sets, so avoiding 160 deaths and 2,000 injuries per year across Europe.  Overall, it is estimated that by using Deca-BDE, gains of between 520 and 1,100 million Euros (650 million to 1.3 billion USD) per year for the entire EU area could be achieved, mainly through saved health care costs and costs relating to damaged property.
You can read the full study in the following link: http://wpy.observer.se/wpyfs/00/00/00/00/00/07/DA/2B/wkr0010.pdf

For more information on the fire safety benefits of flame retardants, please click here

Other relevant documents

Flame retardants and fire safety: Deca-BDE
BFRs and Safety: The Facts about Airplane Safety
Fire safety of cars

Scientific studies

Deca-BDE is the flame retardant with the most scientific data proving its compatibility in terms of human health, low and manageable risks for the environment and its tremendous contribution to society in terms of fire safety. It has been subject to hundreds of scientific studies around the globe, mainly in the European Union, Japan and the United States to assess its potential environmental and human/consumer effects.

In May 2004 the European Union Competent Authorities officially closed the scientific assessment of Deca-BDE without no restrictions due to the lack of risks identified for the use of this substance (see more details below).

These results have been also confirmed by an initial risk assessment conducted by the Japanese government in 2005 which concluded that no adverse health effects were identified for Deca-BDE. In the United States, Deca-BDE has been also subject to extensive research, in particular by the U.S. National Academy of Sciences and in the framework of the Voluntary Children’s Chemical Evaluation Program (VCCEP), which has reached similar conclusions.

The EU Risk Assessment of Deca-BDE

Although not being classified in the EU as a dangerous substance, in 1994 the European Commission Regulation 1179/94 listed Deca-BDE in the Priority List 1 and designated the UK government as the Member State rapporteur for the environmental assessment and the French government for the human health aspect.

After 10 years of scientific research and more than 588 studies conducted and/or reviewed, both the environment and human risk assessment reports concluded that there is no significant risk on these areas. On that basis, the EU Competent Authorities agreed on 26 May 2004 to finalise the risk assessment with no restrictions in the use of Deca-BDE beyond those already in place. Industry committed to initiate an independent biomonitoring program and a further neurotoxicity study, both of which are currently being conducted. The EU Competent Authorities also agreed during the same meeting that issues relating to the environmental findings of Deca-BDE in Europe should be addressed by the initiation of a voluntary industry monitoring programme. This would be complemented by a further voluntary programme of industrial emissions control in partnership with Deca-BDE user industries in Europe, the so-called VECAP program.
Click here to read more about the VECAP program for high production volume brominated flame retardants, including Deca-BDE.

The interim report on the first two years of the environmental monitoring program on Deca-BDE indicates that VECAP seems to have had a direct impact in that it has led to a significant decline in levels of Deca-BDE in the United Kingdom, where the emissions reduction program was initially developed in 2004.

With the introduction of VECAP for Deca-BDE, not only has this substance no significant risk identified but it is now far better controlled through the manufacturing supply chain than any alternatives.

The European Commission Scientific Committee on Health and Environmental Risks (SCHER) adopted an Opinion in March 2005 on the Environmental Risk Assessment of Deca-BDE. The Opinion stated that the risk assessment had been “well done”. Both the European Commission and the UK government, which led the environmental risk assessment, have made clear that the SCHER opinion provided no new evidence demonstrating a risk from Deca-BDE, and that the calls made in the Opinion for risk reduction measures to address the low levels of Deca-BDE found in some environmental studies are already being addressed by the industry’s monitoring and emissions control programmes developed in conjunction with the EU authorities.

The EU risk assessment of Deca-BDE, which has been regularly updated since 2004 to take into account new science, has looked into over 1000 studies performed on Deca-BDE. On December 2007 the EU Member State Competent Authorities met to discuss the latest science available on Deca-BDE and the progress achieved by VECAP. The Committee confirmed the updated Risk Assessment report conclusions. They also agreed that the ongoing scientific and voluntary emission reduction programmes are progressing and committed to reviewing these programmes regularly under REACH.

A consolidated risk assessment text is expected to be published shortly by the European Chemicals Bureau.


Other relevant documents

- Initial Japanese risk assessment
- US VCCEP study
- European Union Risk Assessment report
- SCHER Scientific Opinion on the Environmental Risk Assessment of Deca-BDE
- EBFRIP press release on EU Scientific Opinion on the EU risk assessment of DecaBDE
- Press release on launch by the Utrecht University of the human bio-monitoring programme to assess levels and trends of Deca-BDE
- Press release of the Netherlands Institute for Fisheries Research-RIVO on the European environmental monitoring of Deca-BDE
- Voluntary emissions control action programme leaflet
- VECAP annual progress reports 2006 (click here) and 2007 (click here) for more info
- BSEF statement “EU chemicals assessment authorities confirm no restrictions on Deca-BDE and support ongoing science”, December 2007

 

Regulatory update

The European Union RoHS Directive

The EU Directive to restrict hazardous substances from E&E, bans the use of PBBs, Penta-BDE, and Octa-BDE, among other substances, in the production of new E&E equipment since 1st July 2006.

The polymeric applications of commercial Deca-BDE were exempted from the RoHS Directive on 15 October 2005. This Decision was taken by the European Commission on the basis of the conclusions of the European Union 10-year environmental and human health risk assessment, and of the voluntary emissions reduction programme established by Deca-BDE manufacturing and user industries - VECAP (Click here for the official Decision).

The European Commission also took into consideration the contributions from a stakeholder consultation in July 2004, where a significant majority of responses (85%) were in favor of exempting Deca-BDE (see DG Environment website).

In January 2006 the European Parliament and Denmark both launched legal procedures against the European Commission regarding the exemption of Deca-BDE from the RoHS Directive. In advance of any European Court of Justice ruling, the European Commission Decision to exempt Deca-BDE form the RoHS Directive remains entirely valid and must be implemented since 15 October 2005.

Nordic countries

Despite the European risk assessment outcome on Deca-BDE which identified no risk to human health and the environment, some Nordic governments continue to seek to ban Deca-BDE and other brominated flame retardants reviewed at EU level. BSEF is contributing actively in addressing remaining concerns and working with Nordic stakeholders. At the same time, BSEF is confident the integrity of the European Single Market will hold and EU science-based policy will be successfully implemented.

This unilateral action ignores the results of a comprehensive EU risk assessment of Deca-BDE, which did not identify any risks either to health or to the environment. By contrast to the EU’s scientific conclusions the Norwegian government announced in January 2008 a national ban on the brominated flame retardant Deca-BDE due to enter into effect in April 2008. This announcement follows the 2005 notification by Norway of its intention to restrict Deca-BDE. This had been opposed by the European Commission, the WTO and Norwegian and European industry, who all requested Norway to follow EU procedures and decisions rather than taking a unilateral national measure.

On 21 March 2007, the European Commission sent a letter of formal notice to the Swedish Government making clear that the Commission considers this unilateral measure by the Swedish government to be neither justified on grounds of environmental protection in Sweden, nor necessary and proportional.  This is the first stage in formal EU legal infringement proceedings.  Following this, the European Commission and the Swedish Government are currently in dialogue in order to address the incompatibility of the Swedish measure with European law.

United States

In the United States several States have proposed bills addressing PBDEs. Washington and Maine have enacted partial restrictions on the use of Deca.  There are no other restrictions on the use of Deca-BDE in the U.S.

For detailed information, please visit the United States regulatory updates in http://www.bsef.com/regulation/index.php


Please click here for more information on the regulations referring to brominated flame retardants

Eco labels

The use of Deca-BDE is not restricted under these various eco-labels:

    • EU Eco-flower (EU Commission) criteria for the following product groups: portable and personal PCs, TVs, textiles, mattresses
    • Blue Angel (Germany) - Product groups include PCs, printers & copiers
    • Nordic Swan (Norway, Sweden, Iceland and Finland) - Product groups include PCs, copiers & fax
    • TCO (Sweden) - Product groups include PCs, printers, portables, notebooks, displays

The question of alternatives

Deca-BDE is the most studied flame retardant on the market, having been the subject of an extensive 10-year evaluation by the European Union, as well as other major studies performed by the US Environmental Protection Agency and the US National Academy of Sciences, and has been found to present no significant risks to humans or the environment.

In its areas of application, Deca-BDE is the most effective flame retardant available. Although alternative substances to Deca-BDE exist, there are no alternatives that combine Deca-BDE’s technical efficiency with such rigorous evaluation of potential environmental and human health impacts. Requiring the replacement of Deca-BDE, a product with no identified risks to human health or the environment, with other flame retardants whose potential impacts on human health and the environment are far less understood is not sound public policy.

Please click here to read the factsheet “Deca-BDE and alternative flame retardants”

Waste and recycling

The full cycle of the Deca-BDE product has been evaluated, from initial production through recycling at the end of consumer product life. A number of studies have demonstrated the compatibility of the use of Deca-BDE for recovery and recycling solutions:

  • “TV case study, a life cycle analysis”, SP TV LCA data. Simonson, M., Blomqvist, P., Boldizar, A., Moeller, K., Rosell, L., Tullin, C., Stripple, H., Sundqvist, J.O. Fire-LCA model, 2000. Interscience Communication Ltd., London,
    ISBN 91-7848-811-7.
    • The study demonstrated full compliance with fire safety standards after aged material was recycled and concluded that high impact polysterene plastics (HIPS) containing Deca-BDE carry better physical properties than plastics without BFRs.
  • “Determination of Polybrominated Diphenyl Ethers and PBDD/Fs during the Recycling of High Impact Polystyrene Containing Decabromodiphenylether and Antimony Oxide”. Chemosphere, 44/6 (2001) 1353-1360 Hamm, S.,Strikkeling, M.,Ranken, P.,Rothenbacher, K.P, 2001.
    • High impact polystyrene (HIPS) plastic containing Deca-BDE and antimony oxide was recycled 5 times. The study showed that even after the material was recycled five times no debromination of Deca-BDE into lower brominated diphenyl ethers takes place. Furthermore the 5 times recycled product was fully compatible with the German legislation on dioxin/furans limits in products.
  •  “Recycling of bromine from plastics containing brominated flame retardants in state-of the-art combustion facilities”, Tamara, Vehlow, B. Forschungszentrum Karlsruhe Institut für Technische Chemie Bereich Thermische Abfallbehandlung, Plastics Europe, EBFRIP, 2002.
    • Both pilot studies (carried out by German institute FZK and Plastics Europe) show that brominated flame retardant –including Deca-BDE- contained in WEEE plastics can be safely handled in modern household waste incinerators. The study has concluded that up to 3% WEEE plastics containing BFRs can be safely added to the incinerator. The halogens have a positive cleaning effect on the heavy metals in the slag.
  • E&HS aspects on metal recovery from electronic scrap”. Sweden, Metal and Energy Recovery Conference. Lehner T., Boliden (2003).
    • The study concludes that plastics containing Deca-BDE demonstrate good energy recovery and are fully compatible with metal recycling.

The EU Risk Assessment on Deca-BDE includes a whole section on end-of-life and on dioxins and furans which looks into the various disposal and recovery options including recycling, recovery and landfill. In none of the sections mentioned above significant risks were identified. On landfill, the risk assessment report indicates that “several experiments have shown that leaching of decabromodiphenyl ether from polymers is minimal and it would not be expected to leach to a significant extent from polymers in landfill (…). Any released decabromodiphenyl ether is likely to adsorb strongly onto soil, thus minimising the possibility of reaching groundwater. Similarly, the low vapour pressure of the substance would limit its volatility to the atmosphere.” On incineration, the risk assessment report indicates“ (…) It is expected that emissions from controlled incineration processes will be near zero (…)”.